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Leaching kinetics of low-grade copper ore with high-alkality gangues in ammonia-ammonium sulphate solution

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【作者】 刘志雄尹周澜胡慧萍陈启元

【Author】 LIU Zhi-xiong1,2,YIN Zhou-lan1,HU Hui-ping1,CHEN Qi-yuan1 1.School of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China;2.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,China

【机构】 School of Chemistry and Chemical Engineering,Central South UniversityCollege of Chemistry and Chemical Engineering,Jishou University

【摘要】 The leaching kinetics of low-grade copper ore with high-alkality gangues was studied in ammonia-ammonium sulphate solution.The main parameters,such as ammonia and ammonium sulphate concentrations,particle size,solid-to-liquid ratio and reaction temperature,were chosen in the experiments.The results show that the increase of temperature,concentrations of ammonia and ammonium sulphate is propitious to the leaching rate of copper ore.The leaching rate increases with the decrease of particle size and solid-to-liquid ratio.The leaching rate is controlled by the diffusion through the ash layer and the activation energy is determined to be 25.54 kJ/mol.A semi-empirical equation was proposed to describe the leaching kinetics.

【Abstract】 The leaching kinetics of low-grade copper ore with high-alkality gangues was studied in ammonia-ammonium sulphate solution.The main parameters,such as ammonia and ammonium sulphate concentrations,particle size,solid-to-liquid ratio and reaction temperature,were chosen in the experiments.The results show that the increase of temperature,concentrations of ammonia and ammonium sulphate is propitious to the leaching rate of copper ore.The leaching rate increases with the decrease of particle size and solid-to-liquid ratio.The leaching rate is controlled by the diffusion through the ash layer and the activation energy is determined to be 25.54 kJ/mol.A semi-empirical equation was proposed to describe the leaching kinetics.

【基金】 Project(2007CB613601) supported by the National Basic Research Program of China;Project(10C1095) supported by the Foundation of Hunan Educational Committee,China
  • 【文献出处】 Journal of Central South University ,中南大学学报(英文版) , 编辑部邮箱 ,2012年01期
  • 【分类号】X703
  • 【被引频次】8
  • 【下载频次】66
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