【摘要】 用溶胶—凝胶法制备了La1-xCex MnO3粉体,根据DSC-TGA、FT-IR、XRD分析了样品的晶化过程,用圆柱体法测试了样品的室温电阻率,用微波网络分析仪测试样品的微波吸收性能.结果表明,样品凝胶在煅烧时经过脱水、剧烈分解、逐渐晶化等过程,900℃左右形成稳定的钙钛矿结构并伴有少量CeO2杂相;室温电阻率处于半导体范围,且随掺杂量x增加而减小;样品厚度为2.2 mm、x=0.4时,13.2 GHz频率位置处微波吸收峰值为27 dB,10 dB频宽为3.2 GHz.分析认为,合适的电阻率、钙钛矿晶体极化驰豫及共振、铁磁团簇转向及共振是材料具有良好微波吸收性能的原因.更多还原

【Abstract】 The powder samples of La1-xCexMnO3 were prepared by sol-gel method and their crystallization process was discussed on the basis of DSC-TGA,XRD and FT-IR.Their conductivities at room temperature and microwave absorption properties were measured respectively by cylinder method and microwave network analyzer.The results show that the gel of La1-xCexMnO3 went through dehydration,severe decomposition and gradual crystallization and transformed into a stable perovskite structure with a small amount of CeO2 impurity phase about 900oC when calcined.The resistivites of the samples were within semiconductor area and reduced with Ce content x increase.The effective absorption bandwidth above 10 dB for La1-xCexMnO3 was 3.2 GHz and the absorption peak was 27dB at 13.2 GHz when the thickness was 2.2 mm and x=0.4.From the analysis,it is believed that La1-xCexMnO3 has excellent microwave absorption because of appropriate resistivity,polarization relaxation and resonance of perovskite crystal,and turning and resonance of ferromagnetic clusters in the sample under microwave electromagnetic field.更多还原