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苯乙烯嘧啶化合物的合成及其作为pH探针的光谱特点
Synthesis of Styrylpyrimidine and Its Spectral Characteristic as a pH Probe
【摘要】 合成并表征了化合物4,6-二[(4’-二乙基胺基)苯乙烯基]嘧啶-2-醇。通过研究该化合物在不同pH值的磷酸盐缓冲溶液中紫外-可见吸收光谱和荧光光谱的变化,发现λmax约为500 nm的吸收峰在溶液pH=6.78中吸收强度最大。荧光发射峰随着pH值的升高逐渐减弱,直至淬灭(pH=5.51)。
【Abstract】 4,6-Bis[(4′-diethylamino) styryl] pyrimidin-2-ol was synthesized and characterized.The UV-Vis and fluorescent properties were studied in phosphate buffer solutions at different pH value.The UV-Vis spectral results indicated that the peak located at ~500 nm reaches maximal intensity at pH=6.78.The fluorescent spectra data suggested that the intensity of emission peak decreased with increasing pH value.The fluorescence was quenched when the pH was 5.51.
【关键词】 苯乙烯嘧啶;
pH探针;
吸收光谱;
荧光光谱;
【Key words】 styrylpyrimidine; pH probe; absorption spectrum; fluorescence spectrum;
【Key words】 styrylpyrimidine; pH probe; absorption spectrum; fluorescence spectrum;
【基金】 河南省高校科技创新人才基金(2010HASTIT025);河南省科技创新人才项目(104100510020);河南省教育厅自然科学研究项目(2009A150023)资助
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2012年11期
- 【分类号】O626.41
- 【被引频次】2
- 【下载频次】108