【摘要】 以1,3-二苯基丙酮为原料,经干燥的H2S和HCl气体反应得二苄基二巯基甲烷(1),在微波辐射条件下,经酯化、肼解,得1,1-二苄基-1,1-二硫乙酰肼(3),再与芳香醛反应,方便地合成了酰腙类新化合物(4a～4n)。其结构经IR、1H NMR、MS和元素分析确证。更多还原

【Abstract】 Using 1,3-diphenylacetone as precursor,bibenzyldithiolmethane(1) was prepared through reacting 1,3-diphenylacetone with dry hydrogen sulfide and hydrogen chloride.Under microwave irradiation,compound 1 was subjected to esterification and hydrazinolysis to yield 1,1-bibenzyl-1,1-bimercaptoacetyl-hydrazine(3).The condensation reactions between compound 3 and aromatic aldehyde led to the production of a series of 1,1-bibenzyl-1,1-bimercaptoacetylhydrazone(4a~4n).Their structures were confirmed by IR,1H NMR,MS and elemental analysis.更多还原