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Luminescence properties of SrB4O7:Sm2+ for light conversion agent

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【作者】 孙家跃朱吉成刘晓瑭杜海燕

【Author】 SUN Jiayue1,ZHU Jicheng1,LIU Xiaotang2,DU Haiyan 1 (1.School of Sciences,Beijing Technology and Business University,Beijing 100048,China; 2. College of Sciences,South China Agricultural University,Guangzhou 510642,China)

【机构】 School of Sciences,Beijing Technology and Business UniversityCollege of Sciences,South China Agricultural University

【摘要】 A deep red-emitting SrB4O7:Sm2+ phosphor for light conversion agent was synthesized by the conventional solid-state reaction. X-ray powder diffraction (XRD) analysis confirmed the phase formation of SrB4O 7:Sm2+ materials. Results of luminescence properties showed that the phosphor could be efficiently excited by the UV-vis light region from 250-500 nm, and it exhibited deep red (685 nm) emission corresponding to 5D0 → 7F0 transition of Sm 2+ . The critical quenching concentration of Sm 2+ in SrB4O7 :Sm 2+ phosphor was about 0.05, and the corresponding concentration quenching mechanism was verified to be the dipole-dipole interaction according to the Dexter’s theory. The decay times had few alterations with different concentrations in SrB4O7:xSm 2+ phosphor.

【Abstract】 A deep red-emitting SrB4O7:Sm2+ phosphor for light conversion agent was synthesized by the conventional solid-state reaction. X-ray powder diffraction (XRD) analysis confirmed the phase formation of SrB4O 7:Sm2+ materials. Results of luminescence properties showed that the phosphor could be efficiently excited by the UV-vis light region from 250–500 nm, and it exhibited deep red (685 nm) emission corresponding to 5D0 → 7F0 transition of Sm 2+ . The critical quenching concentration of Sm 2+ in SrB4O7 :Sm 2+ phosphor was about 0.05, and the corresponding concentration quenching mechanism was verified to be the dipole-dipole interaction according to the Dexter’s theory. The decay times had few alterations with different concentrations in SrB4O7:xSm 2+ phosphor.

【基金】 supported by Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality (PXM 2011_014213_113560,113522);the Cooperation Project in Industry,Education and Research of Guangdong Province and Ministry of Education of China (2011B090400100)
  • 【文献出处】 Journal of Rare Earths ,稀土学报(英文版) , 编辑部邮箱 ,2012年11期
  • 【分类号】O614.3
  • 【被引频次】4
  • 【下载频次】64
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