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掺杂浓度和烧结温度对CaWO4:Eu3+发光性能的影响
Effects of doping concentration and sintering temperature on luminescence of CaWO4:Eu3+ phosphor
【摘要】 采用微乳液法合成掺杂浓度不同和烧结温度不同的CaWO4:Eu3+系列荧光体,这些荧光体都具有Eu3+离子的特征荧光发射.在不同温度烧结后,高浓度掺杂的样品(Eu3+掺杂30或50 mol%)可获得最大的发光强度,低浓度掺杂的样品(掺杂0.5—2 mol%)在800℃烧结时也可获得优异的发光强度.实验结果表明,Eu3+离子高浓度掺杂的CaWO4:Eu3+在紫外光激发下可成为高效发光的荧光粉.
【Abstract】 The CaWO4:Eu3+ phosphors with different doping concentrations and different sintered temperatures are synthesized using the microemulsion reaction method.After sintered at different temperatures,the samples with doping concentration of 30 or 50 mol% can obtain the brightest characteristic emissions from Eu3+ ions.At 800℃,moreover,the samples with doping concentrations of 0.5—2 mol%can emit the strongest light.It is therefore concluded that more intense emissions enable the CaWO4:Eu3+ phosphors with high doping concentrations to have great potential to be used as efficient phosphors in the future.
【Key words】 CaWO4:Eu3+; Judd-Ofelt theory; doping concentration; photoluminescence;
- 【文献出处】 物理学报 ,Acta Physica Sinica , 编辑部邮箱 ,2012年07期
- 【分类号】O482.31
- 【被引频次】28
- 【下载频次】418