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TiO2-石墨烯光催化剂:制备及引入石墨烯的方法对光催化性能的影响

TiO2-Graphene Photocatalyst:Preparation and Effect of the Introducation of Graphene on Photocatalytic Performance

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【作者】 耿静漪朱新生杜玉扣

【Author】 GENG Jing-Yi1,2 ZHU Xin-Sheng ,1 DU Yu-Kou ,2(1College of Textile and Clothing Engineering,Soochow University,Suzhou 215123,China)(2College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou 215123,China)

【机构】 苏州大学纺织与服装工程学院苏州大学化学化工学院

【摘要】 利用溶胶-凝胶法原位制备了二氧化钛/石墨烯(TiO2-GE)复合光催化剂,研究了纯TiO2以及不同方法制备的TiO2-GE复合光催化剂对亚甲基蓝及罗丹明B光催化降解性能。结果表明:石墨烯的引入提高了TiO2的光催活性,这主要是得益于石墨烯优异的电子传输性能及较好吸附特性。不同方法制备TiO2-GE复合催化剂的光催化活性也存在较大差别。原位制备的TiO2-GE复合光催化剂表现出最佳的光催化活性。

【Abstract】 Titania/graphene(TiO2-GE) composite photocatalyst has been in-situ synthesized by sol-gel method.The photocatalytic performance of pure TiO2 and TiO2-GE composite obtained by different methods has been investigated using the photodegradation of methylthionine chloride and rhodamine B as model reactions.The results show that the photocatalytic activity of TiO2-GE composite is much higher than that of pure TiO2 due to rapid electronic transmission and the good adsorption of GE.Additionally,the as-prepared TiO2-GE composites obtained with different preparation methods have different activities in the photodegradation of methylthionine chloride and rhodamine B.The TiO2-GE composite synthesized by in-situ sol-gel method shows the highest photocatalytic activity.

【关键词】 溶胶-凝胶法TiO2-GE光催化活性
【Key words】 sol-gelTiO2-GEphotocatalytic activity
【基金】 国家自然科学基金(No.51073114)资助项目
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2012年02期
  • 【分类号】O643.3
  • 【被引频次】93
  • 【下载频次】3251
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