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HPER的制备及在NR中的应用研究

Research on the preparation of hyper-branched pentaerythritol(HPER) and its application in NR composites

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【作者】 王锦成郭曦吴鼎郑晓昱郝文莉赵艺

【Author】 WANG Jin-cheng,GUO Xi,WU Ding,ZHENG Xiao-yu,HAO Wen-li,ZHAO Yi(College of Chemistry and Chemical Engineering,Shanghai University of Engineering Science,Shanghai 201620,China)

【机构】 上海工程技术大学化学化工学院

【摘要】 首先对季戊四醇(PER)进行超支化有机改性,然后采用磷酸封端,制得磷系阻燃剂——超支化季戊四醇(HPER)。采用共混法制备了天然橡胶(NR)/HPER复合材料,研究了其阻燃和物理机械性能。结果表明,与未添加阻燃剂的NR相比,NR/HPER复合材料的水平燃烧时间得到延长,同时其硬度降低,拉伸强度与断裂伸长率有着不同程度的提高。

【Abstract】 Pentaerythritol was modified by hyper-branched technology and was endcapped with phosphate,and thus phosphorus type of flame-retardant agent,hyper-branched pentaerythritol(HPER),was obtained.Natural rubber(NR)/HPER composites were prepared by blending methods,and their flame-retardant and physico-mechanical properties were studied.Results showed that the horizontal burning time of NR/HPER composites was prolonged,their hardness was decreased,tensile strength,and elongation at break were improved compared with that of pure NR composite.

【基金】 国家自然科学基金项目(50803034,51173102);上海市曙光计划项目(10SG53);上海高校知识创新工程建设项目(JZ0904);上海市科委地方高校能力建设项目(11490501500);大学生科研创新计划项目(2012xs57)
  • 【分类号】TQ332.5
  • 【下载频次】46
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