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交联薯渣黄原酸酯对废水中Cr(Ⅵ)的吸附研究

Study of adsorption of chromium(Ⅵ) from aqueous solution by crosslinked cassava residue xanthate

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【作者】 石金亨林宝凤肖定书胡继文

【Author】 SHI Jin-heng1,2,LIN Bao-feng1,XIAO Ding-shu2,HU Ji-wen2(1.College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China;2.Guangzhou Institute of Chemistry,Chinese Academy of Sciences,Guangzhou 510650,China)

【机构】 广西大学化学化工学院中国科学院广州化学研究所

【摘要】 交联薯渣黄原酸酯(CCX)废水中Cr(Ⅵ)离子的吸附,探讨了pH值、温度、吸附时间、CCX含硫量、Cr(Ⅵ)初始浓度等因素对其吸附效果的影响。结果表明,当CCX加入量为理论加入量的3.0倍时,pH为2.5,在45℃下搅拌反应50 min,对Cr(Ⅵ)的吸附容量为37.76 mg/g,去除率达到99.69%,处理后的废水中Cr(Ⅵ)浓度为0.15 mg/L,低于国标排放标准(0.5 mg/L)。并通过红外光谱和热重分析,对CCX吸附Cr(Ⅵ)的机理进行了探讨。

【Abstract】 Adsorption of chromium(Ⅵ) from aqueous solution by crosslinked cassava residue xanthate was studied.The effect of pH value,temperature,adsorption time,sulfur content of CCX,initial concentration of chromium(Ⅵ) on the efficiency of chromium(VI) ion-removal were investigated.It was found that when the CCX amount was 3.0 times of its theoretical amount,pH value was 2.5,and the time for agitating at 45 ℃ was 50 min,the adsorption capacity of Cr(VI) was 37.76 mg/g,the Cr(VI) removal efficiency was up to 99.69%,and the concentration of Cr(Ⅵ) in treated waste water was 0.15 mg/L,which was lower than the national standard emission standards(0.5 mg/L).The adsorption mechanism of chromium(Ⅵ) by crosslinked cassava residue xanthate was discussed with infrared spectroscopy and thermogravimetric analysis.

【基金】 科技部项目(2009GJE10048);广西南宁市科技攻关项目(201003068G);广西大学科研基金项目(XBZ110331)
  • 【文献出处】 应用化工 ,Applied Chemical Industry , 编辑部邮箱 ,2012年04期
  • 【分类号】X703
  • 【被引频次】3
  • 【下载频次】95
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