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一种胺型吸附材料的制备及对铜离子吸附性能的研究

Study of Adsorption Properties of a New Chelating Adsorption Material of Amidocyanogen for Cu2+

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【作者】 胡军徐国亮曾科赵春娥李文栋朱俊赵永超申晓华杨刚

【Author】 HU Jun, XU Guo-liang, ZENG Ke, ZHAO Chun-e, LI Wen-dong, ZHU Jun, ZHAO Yong-chao, SHEN Xiao-hua, YANG Gang(Application and Research Center for Electron Been of College of Polymer-NHVC, College of Polymer Science &Engineering, State Key Laboratory of Polymer Material Engineering(Sichuan University), Chengdu 610065, China)

【机构】 四川大学高分子学院-NHVC电子线应用研究中心,高分子科学与工程,高分子材料工程国家重点实验室(四川大学)

【摘要】 在氮气氛围中利用低能电子束预辐照接枝法,在低密度聚乙烯(LDPE)上接枝丙烯腈(AN)进而通过酸性水解、霍夫曼降解,制备一种胺型螯合树脂(LDPE-g-VAm),并考察这种螯合吸附材料对铜离子的吸附性能;研究了铜离子的质量浓度、吸附时间、pH值及循环次数对铜离子螯合吸附能力的影响规律;同时对吸附材料进行全反射红外(FT-IR)的表征。

【Abstract】 A study was made on the preparation of a chelating material with amidocyanogen by three steps ,including pre-irradiation grafting of acrylonitrile(AN) onto low-density polyethylene(LDPE) membrane,hydrolysis in acid conditions and Hofman degradation. The equilibrium sorption for Cu2+ was studied and the effect of mass concentration of Cu2+,time and pH on sorption capacity were also discussed . The result showed that this kind of resin had strong absorbing ability to Cu2+, and the structure of the material was characterized by FTIR.

  • 【分类号】O647.31
  • 【被引频次】1
  • 【下载频次】154
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