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热处理对超级马氏体不锈钢腐蚀性能的影响

Effect of heat treatment on corrosion performance of supermartensitic stainless steels

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【作者】 徐军李俊姜雯业冬龙晋明雍歧龙苏杰赵昆渝

【Author】 XU Jun1,LI Jun1,JIANG Wen,YE Dong1,LONG Jin-ming1, YONG Qi-long2,SU Jie2,ZHAO Kun-yu1(1.College of Materials Science and Engineering,Kunming University of Science and Technology, Kunming 650093,Yunnan,China;2.Institute of Structural Materials,Central Iron and Steel Research Institute,Beijing 100081,China.)

【机构】 昆明理工大学材料科学与工程学院钢铁研究总院结构材料研究所

【摘要】 对两种(含W、Cu,不含W、Cu)超级马氏体不锈钢(SMSS)进行1050℃保温0.5 h后淬火及不同温度(550℃、650℃、750℃)保温2 h的回火处理,在饱和CO2浓度下,Cl-浓度为2.12%的NaCl溶液中采用电化学方法研究其耐蚀性能。循环极化曲线分析结果证实,回火温度对耐腐蚀性能有重要影响,并且550℃时耐腐蚀性能最好;含W、Cu的SMSS具有较高的点蚀电位。交流阻抗分析表明,回火温度为550℃的样品具有最高的阻抗值,形成的钝化膜最稳定。

【Abstract】 Two kinds(W,Cu-free;W,Cu-containing) of supermantensitic stainless steels(SMSS) were quenched after solution treatment at 1050 ℃ for 0.5 h,then tempered at 550 ℃,650 ℃,750 ℃ for 2 h.The corrosion performance was surveyed by electrochemical methods in CO2-saturated NaCl solution with the chloride content of 2.12%.The results of cyclic polarization curves indicate that the tempering temperature has significant effect on corrosion resistance of the steel,and the specimen has the best corrosion resistance when tempered at 550 ℃.The pitting potential of SMSS increases by the addition of tungsten and copper.Alternating current impedance(AC impedance) curves show that the specimen which is tempered at 550 ℃ has the maximum impedance,and the most stable passive film is formed.

【基金】 先进钢铁材料技术国家工程研究中心项目
  • 【文献出处】 材料热处理学报 ,Transactions of Materials and Heat Treatment , 编辑部邮箱 ,2012年03期
  • 【分类号】TG161
  • 【被引频次】5
  • 【下载频次】480
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