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Tenax-TA吸附联合气相色谱-质谱仪测定密闭环境苯系物

Tenax-TA Adsorption Combined Gas Chromatography-mass Spectrometry for Monitoring BTX in Airtight Environment

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【作者】 郭莉华何新星丁军平徐国鑫祁欣

【Author】 Guo Lihua,He Xinxing,Ding Junping,Xu Guoxin,Qi Xin. Beijing University of Chemical Technology,Beijing 100029,China

【机构】 北京化工大学中国航天员科研训练中心

【摘要】 目的探讨Tenax-TA吸附管对密闭环境中苯系物的吸附性能。方法依据《室内空气质量标准》总挥发性有机物的测定方法和美国EPA TO-17标准方法,用Tenax-TA吸附管对配制的苯系物标准气体进行采样,以保留时间定性,峰面积定量。结果该方法对苯系物测定的相对标准偏差在4.50%~9.51%之间,苯、甲苯、对二甲苯、邻二甲苯的最低检出浓度分别为0.04,0.65,0.50和1.60μg/m3。当采样体积不大于3 L时,Tenax-TA采样管没有穿透现象发生,苯系物通过Tenax-TA管吸附采样后在室温下可以保存40 d。结论 Tenax-TA吸附管对苯系物具有良好的吸附性能,而且设备简单,样品保存时间长,适合于一些特殊环境中气体的采集。

【Abstract】 Objective To investigate the adsorption performance of Tenax-TA tube to Benzene,Toluene,P-xylene,O-xylene in airtight environment.Methods Instruments methods were established according to Indoor Air Quality Standard and EPA TO-17 method of USA.BTX standard samples were collected with Tenax-TA adsorption tube.Qualitative and quanlysis analysis of spectrums were made respectively with retention time and peak area.Results The relative standard deviation of Benzene,Toluene,P-xylene,O-xylene was 4.50%~9.51%.The minimum detectable concentration of Benzene,Toluene,P-xylene,O-xylene were detected,which were 0.04,0.65,0.50,1.60 μg/m3 respectively.When sampling volume was not more than 3 L,the breakthrough did not happen.The storage time of Tenax-TA tube with BTX was 40 d at indoor temperature.Conclusion Tenax-TA tube has good adsorption to BTX.The simple equipment and long storage time of sample made the gas-collecting in special environment possible.

【关键词】 Tenax-TA吸附管热解吸苯系物
【Key words】 Tenax-TAadsorption tubesthermal desorptionBTX
【基金】 中国载人航天预先研究项目(010204)
  • 【文献出处】 航天医学与医学工程 ,Space Medicine & Medical Engineering , 编辑部邮箱 ,2012年02期
  • 【分类号】X831;O657.63
  • 【被引频次】4
  • 【下载频次】293
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