【摘要】 本文分别从以骨架中的金属(金属簇)为催化中心的MOF材料、利用具有催化活性的刚性有机配合物构筑的MOF材料和MOF负载催化材料三个方面详细介绍了MOF作为催化剂在烯烃氧化反应中的应用情况,分析了其各自的优缺点。具有催化活性的刚性有机配合物构筑的MOF材料稳定性较好,能够引入具有光学活性的催化剂,可以作为不对称催化氧化催化剂使用,是未来的一个研究发展方向。更多还原

【Abstract】 As a new class of porous solids,metal-organic frameworks(MOFs) have attracted a great deal of interests of chemists in the world due to their unique properties,such as the high specific surface area,tailoring structure properties and 100% utilization of exposed metal ions.The chemical and structural versatility of such materials makes them potentially candidates for applications in catalysis.In this review,we focus our attention on olefins oxidation using MOF as catalysts.Three classes of MOF catalysts are active site at the inorganic nodes on the MOF,active site at the organic or pseudo-organic linkers,and MOF-supported active specie.The applications of the three classes of MOF catalysts on the olefins oxidation are discussed in detail.更多还原