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Nd掺杂对BiFeO3薄膜微结构和电学性能的影响

The effect of Nd doping on microstructure and electrical properties of BiFeO3 thin films

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【作者】 高成杨静孟祥建白伟林铁孙璟兰褚君浩

【Author】 GAO Chen1,YANG Jing2,MENG Xiang-Jian1,BAI Wei2, LIN Tie1,SUN Jing-Lan1,CHU Jun-Hao1,2(1.National Laboratory for Infrared Physics,Shanghai Institute of Technical Physics,Chinese Academy of Sciences,Shanghai 200083,China; 2.Key Laboratory for Polar Materials and Devices of Ministry of Education,East China Normal University,Shanghai 200241,China)

【机构】 中国科学院上海技术物理研究所红外物理国家重点实验室华东师范大学极化材料与器件教育部重点实验室

【摘要】 采用化学溶液方法,在LaNiO3/Si(100)衬底上生长了Nd掺杂的BiFeO3薄膜.XRD分析结果表明,随着Nd掺杂量的增加,薄膜晶格变小,Nd掺杂量为20%时,薄膜出现杂相.介电测试表明,随着Nd掺杂量的增加,介电常数和损耗减小,Nd掺杂量为2%的薄膜表现出很强的介电色散现象并出现介电损耗弛豫峰,其符合类德拜模型特征.随着Nd掺杂量增加,薄膜的漏电流减小,在低电场下,电流输运遵从SCLC模型,在高场下,电流输运遵循Poole-Frenkel模型.分析结果表明Nd掺杂对薄膜微结构和电学性能有显著影响.

【Abstract】 The Nd doped BiFeO3 thin films are prepared on LaNiO3/Si(100) substrate by chemical solution deposition method.The results of x-ray diffraction show that the lattice constant of thin films decreases with the increase of Nd content.The impurity phases are found in the thin film with 20% Nd content.The results of dielectric measurement indicate that the dielectric constant and loss of thin films decrease with the increase of Nd content.A very strong dielectric frequency dispersion and relaxation of dielectric loss peak occurs in the thin film with 2% Nd content and it follows Debye-like law.The leakage current of thin films decreases with the increase of Nd content.The current transport follows SCLC model in low electric field region and follows Poole-Frenkel model in high electric field region.These results suggest that Nd doping has a strong influence on microstructure and electric properties of BiFeO3 thin films.

【基金】 国家自然科学基金(60221502,60777044,50702036);上海市自然科学基金(10DJ1400202)~~
  • 【文献出处】 红外与毫米波学报 ,Journal of Infrared and Millimeter Waves , 编辑部邮箱 ,2012年01期
  • 【分类号】O484.1
  • 【被引频次】6
  • 【下载频次】197
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