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鸟粪石沉淀法用于养猪场污水前处理的影响因素研究

Optimizing Conditions for Struvite Precipitation as Pre-treatment of Swine Wastewater

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【作者】 张冬梅程丽华郭小慧韩志英陈英旭吴伟祥

【Author】 ZHANG Dongmei1,2,CHENG Lihua1,GUO Xiaohui2,HAN Zhiying2,CHEN Yingxu2,WU Weixiang2 (1.College of Chemical and Environmental Engineering,Guangdong University of Petrochemical Technology,Maoming 525000,China; 2.Institute of Water Science and Environmental Engineering,Zhejiang University,Hangzhou 310029,China)

【机构】 广东石油化工学院化工与环境工程学院浙江大学水环境研究院

【摘要】 用鸟粪石沉淀法对养猪场污水进行前处理,研究了各类因素对沉淀效果的影响,包括加药剂与调节pH的顺序、搅拌速率、温度、反应时间、溶液pH与加入的药剂量等,其中溶液pH与加入的药剂量是影响养猪场污水中污染物去除的决定性因素.本实验条件下,P/Mg/N比为1/1/1.2、pH10.0时,有最佳NH4+-N的去除率与最低PO34--P的残留质量浓度,分别是87%和30.21 mg/L.

【Abstract】 This study developed a novel pre-treatment of swine wastewater through a stirring precipitation process of struvite formation that could trim down the pollutants loaded,and thus enhance the efficiency of further treatment.The major focus was on optimizing the quantitative factors influencing the struvite precipitation,e.g.,P/Mg/N ratio of chemicals,pH value,stirring speed,temperature,and reaction time.The pH and amount of chemicals being added in the wastewater were the key factors influencing the precipitation of struvite.Results of our experiment indicated that a P∶ Mg∶ N ratio of 1∶ 1∶ 1.2 and pH 10.0 were the optimal conditions.Under these conditions,the removal efficiency of NH+4-N was 87%;and it brought down residual PO3-4-P to the lowest concentration of 30.2 mg/L in the swine wastewater.

【基金】 国家科技重大专项(2008ZX07101-006-04);广东省科技计划项目(2011A030600011)
  • 【文献出处】 华南师范大学学报(自然科学版) ,Journal of South China Normal University(Natural Science Edition) , 编辑部邮箱 ,2012年02期
  • 【分类号】X713
  • 【被引频次】11
  • 【下载频次】282
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