【摘要】 用手性(Salen)Co(Ⅱ)催化(±)-3-氯氧化苯乙烯的水解动力学拆分反应,以高收率得到光学纯的(R)-3-氯氧化苯乙烯(98.4%e.e)及(S)-1-(3-氯苯基)-1,2-乙二醇(89.5%,e.e)。更多还原

【Abstract】 (R)-3-Chlorostyrene oxide and(S)-1-(3-chlorophenyl)-1,2-ethanediol were prepared in good yield and high stereoselectivity(98.4% ee and 89.5% e.e,respectively)from(±)-3-chlorostyrene oxide via chiral(Salen)Co catalyzed hydrolytic kinetic resolution.更多还原