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水系胶体Zeta电位的电声法测量

Electroacoustic Measurement of Zeta Potential in Aqueous Colloids

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【作者】 龚智方苏明旭蔡小舒

【Author】 GONG Zhi-fang 1,2 , SU Ming-xu 1 CAI Xiao-shu 1 (1. Institute of Particle and Two-phase Flow Measurement, University of Shanghai for Science & Technology, Shanghai 200093, China; 2. Technology Center of SAIC MOTOR Co. Ltd., Shanghai 210804, China)

【机构】 上海理工大学颗粒与两相流测量技术研究所上海汽车集团股份有限公司技术中心

【摘要】 基于电声法原理研制了一种能同时用于胶体声阻抗和Zeta电位测量的电声探头,建立了一套测量胶体Zeta电位的实验装置,多次实验证明设备稳定性良好.通过多次回波测量声阻抗计算Zeta电位,测得纳米黄土及TiO2胶体的Zeta电位分别为-52.69和-16.09mV,分析了5%~30%(ψ)SiO2胶体的Zeta电位变化趋势,表明该方法可用于高浓度胶体测量,与马尔文公司光脉动Zeta电位测量仪测量结果偏差较小.本方法有望实现在线测量Zeta电位.

【Abstract】 An electroacoustic probe was developed for measuring acoustic impedance and Zeta potential in colloids simultaneously. Meanwhile, a set of experimental device was established and its stability verified to be good after repeated experiments. Measured acoustic impedance by multiple echo method was incorporated into a theoretical model to calculate Zeta potential. The measurements of Zeta potential in the colloids of nano-loess and nano-titanium dioxide were -52.69 and -16.09 mV, respectively. Zeta potential trend of 5%~30% volume concentration colloids of silica sol was measured and analyzed, showing that the method can be used for high concentration plastic body measurement. The comparison with the results of Malvern Zeta potential measurement instrument yielded a small and accepted deviation. This method is expected to achieve on-line measurement.

【关键词】 胶体电声法Zeta电位
【Key words】 colloidelectroacousticsZeta potential
【基金】 自然科学基金资助项目(编号:51176128;1076106);上海市教委重点基金资助项目(编号:12ZZ142)
  • 【文献出处】 过程工程学报 ,The Chinese Journal of Process Engineering , 编辑部邮箱 ,2012年06期
  • 【分类号】O648.1
  • 【被引频次】9
  • 【下载频次】424
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