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新型无机-有机化合物(C13H16N2)2Mo8O26的合成与晶体结构
Synthesis and Crystal Structure of a New Type Inorganic Organic Mo8O26(C13H16N2)2
【摘要】 采用水热反应合成了一个无机-有机杂化的β-{Mo8O26}簇合物(C13H16N2)2Mo8O26,并通过FTIR光谱和X-射线单晶衍射对其结构进行了分析.分析结果表明该化合物包含了孤立的β-{Mo8O26}4-簇阴离子和2条二维C13H16N2链,分子之间通过氢键作用连结成三维结构的超分子.
【Abstract】 An inorganic and organic hybrid β-{Mo8O26} cluster compound Mo8O26(C13H16N2) is synthetized by hydrothermal synthesis method and its structure are analyzed by the FTIR spectrun and X-ray monocrystal diffraction.The results of the analysis show that the compound contains isolated β-{Mo8O26} 4-cluster anion and two C13H16N2 chains,the molecules form 3d supramolecular structure through hydrogen bonding.
【基金】 哈尔滨师范大学青年学术骨干资助项目(09XBKQ11)
- 【文献出处】 哈尔滨师范大学自然科学学报 ,Natural Science Journal of Harbin Normal University , 编辑部邮箱 ,2012年04期
- 【分类号】O641.4
- 【下载频次】50