【摘要】 以联邻甲苯胺和1-苯基-3-甲基-4-苯甲酰基吡唑啉酮(PMBP)为原料,采用固相法合成了两种新型Schiff碱——联邻甲苯胺单缩PMBP(L’)和联邻甲苯胺双缩PMBP(L);L分别与Cu(Ⅱ),Ni(Ⅱ)和Co(Ⅱ)配合制得三个对应的Schiff碱配合物,其结构经UV,1H NMR,IR和元素分析表征。更多还原

【Abstract】 Two novel Schiff bases,tolidine-PMBP(L′) and tolidine-bisPMBP(L),were synthesized from ortho-tolidine and 1-phenyl-3-methyl-4-benzoyl-pyrazolone(PMBP) by solid method.Three complexes of L with Co(Ⅱ),Cu(Ⅱ) or Ni(Ⅱ) were prepared.The structures were characterized by UV,1H NMR,IR and elemental analysis.更多还原