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三种土壤矿物对苄嘧磺隆的吸附研究

Study on Adsorption of Bensulfuron-methyl by Three Kinds of Soil Minerals

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【作者】 叶发兵黄春保熊绪杰董元彦

【Author】 YE Fa-bing1,2,HUANG Chun-bao2,XIONG Xu-jie2,DONG Yuan-yan3 (1.School of Chemical Engineering,Huanggang Normal University,Huanggang 438000,Hubei,China; 2.Key Laboratory for Economic Germplasm Modification and Product Comprehensive Utilization of Hubei Province,Huanggang 438000,Hubei,China; 3.Department of Chemistry,College of Science,Huazhong Agricultural University,Wuhan 430070,China)

【机构】 黄冈师范学院化工学院湖北省经济林木种质改良与林产品综合利用重点实验室华中农业大学理学院化学系

【摘要】 利用平衡吸附法研究了3种土壤矿物对苄嘧磺隆的吸附及尿素对吸附的影响。结果表明,3种土壤矿物对苄嘧磺隆的吸附符合Langmuir和Freundlich方程,非晶形氧化铝对苄嘧磺隆的最大吸附量最高,为634.5μg/g;针铁矿的最大吸附量为225.9μg/g;高岭土对苄嘧磺隆的最大吸附量最小,为188.9μg/g。尿素的加入使得苄嘧磺隆在非晶形氧化铝、针铁矿表面的吸附量都有不同程度的下降,其中非晶形氧化铝降低的幅度最大;但尿素和苄嘧磺隆同时添加或者先加尿素再加苄嘧磺隆,高岭土对苄嘧磺隆的吸附量都增大。

【Abstract】 Adsorption of bensulfuron-methyl by kaolinite,goethite and amorphous alumina and the effect of urea on the adsorption were examined by equilibrium adsorption method.Results indicated that the adsorption was in accordance with Langmuir equation,with the maximum absorbing capacities ranking as amorphous alumina(634.5 μg / g),goethite(225.9 μg / g),kaolinite(188.9 μg / g).When urea was added in the adsorption system,the absorbing capacities of goethite and amorphous alumina to bensulfuron-methyl decreased whatever the addition order of urea and bensulfuron-methyl was.However,when urea was added before or simultaneously with bensulfuron-methyl in suspension of kaolinite,the adsorption quantity of bensulfuron-methyl was increased.

【关键词】 苄嘧磺隆吸附土壤矿物尿素
【Key words】 bensulfuron-methyladsorptionsoil mineralsurea
【基金】 湖北省教育厅科学研究重点项目(D20092702)
  • 【文献出处】 湖北农业科学 ,Hubei Agricultural Sciences , 编辑部邮箱 ,2012年03期
  • 【分类号】S482.46
  • 【被引频次】3
  • 【下载频次】99
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