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二氧化双环戊二烯改性树脂基复合材料的制备与性能

Preparation and Performance of Dicyclopentadiene Dioxide Modified Epoxy Resin Matrix Composite

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【作者】 吕文丽肖加余徐旺生曾竟成邢素丽蒋卫和

【Author】 Wenli Lv1,2,Jiayu Xiao2,Wangsheng Xu1,Jingcheng Zeng2,Suli Xing2,Weihe Jiang3(1.College of Chemcial Engineering and Pharmacy,University of Wuhan Institute of Technology,Wuhan 430073,China;2.College of Aerospace and Material Engineering,University of DefenseTechnology,Changsha 410073,China;3.ChangDe Chemcial Corporation Limited,Yueyang414004,China)

【机构】 武汉工程大学化工与制药学院国防科学技术大学航天与材料工程学院湖南岳阳昌德化工实业有限公司

【摘要】 采用双酚A型环氧树脂(E-51)改性二氧化双环戊二烯树脂(CDR-0122),以改善其力学性能。首先根据复合材料力学性能选择较好的稀释剂,然后比较树脂基体在改性前后的玻璃纤维(Gf)和炭纤维(Cf)复合材料的基本力学性能和耐热性能。结果表明,环己二醇二缩水甘油醚(CDX-1180)是优于丙酮的一种稀释处理剂。同时用CDX-1180做稀释剂处理时,树脂基体经改性后,所制得的Gf层合板拉伸强度和拉伸模量分别提高了19.1%和16.8%,弯曲强度和弯曲模量分别提高了20.5%和12.6%;所制得的Cf层合板拉伸强度和拉伸模量分别提高了9.7%和8.7%,弯曲强度和弯曲模量分别提高了26.2%和7.0%;E-51改性CDR-0122树脂复合材料相比纯的CDR-0122树脂复合材料的玻璃化转变温度和热稳定性都略有提高。

【Abstract】 In order to improve the mechanical properties of the dicyclopentadiene dioxide(CDR-0122),a bisphenol epoxy resin(E-51)is used.The mechanical properties of glass fiber enhanced polymer-composites with two different diluents were compared to choose the better one.And the mechanical properties and heat-resisting performance of glass fiber(Gf) and carbon fiber(Cf) enhanced composites before and after modification were investigated.The results indicate that the diluent CDR-1180 was better.Simultaneously,using CDX-1180 as the diluent,the tensile strength and modulus of the modified resin matrix glass fiber composites(Gf) increase by 19.1% and 16.8%,respectively,and the bending strength and modulus increase by 20.5% and 12.6%,respectively;the tensile strength and modulus of the modified Cf filled composites increase by 9.7% and 8.7%,respectively,and the bending strength and modulus increase by 26.2% and 7.0%,respectively.The glass transition temperature and thermal stability of the E-51 modified CDR-0122 composites are slightly increased.

【基金】 武器装备预研基金项目(9140A27030309KG01)
  • 【文献出处】 高分子材料科学与工程 ,Polymer Materials Science & Engineering , 编辑部邮箱 ,2012年11期
  • 【分类号】TQ323.5
  • 【被引频次】1
  • 【下载频次】168
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