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Ag-TiO2复合纳米颗粒的自组装法制备及其光催化性

Fabrication of Ag-TiO2 Composite Nanoparticles by Self-Assembly and Their Photocatalytic Activity

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【作者】 王新刘孝恒汪信彭贞薛建跃

【Author】 Wang Xin1,2, Liu Xiaoheng1, Wang Xin1, Peng Zhen2, Xue Jianyue1,2(1. Key Laboratory of Soft Chemistry and Functional Materials of the Ministry of Education,Nanjing University of Science and Technology, Nanjing 210094, China)(2. Chaohu College, Chaohu 238000, China)

【机构】 南京理工大学软化学与功能材料教育部重点实验室巢湖学院

【摘要】 采用空气-水界面自组装法制备TiO2纳米粒子,将其放入AgNO3溶液中浸泡,后在较低温度下进行热处理(400℃),获得Ag-TiO2复合纳米颗粒。利用X射线衍射(XRD)仪、扫描电镜(SEM)、透射电镜(TEM)、紫外可见光谱(UV-Vis)等分析测试手段进行表征。结果表明:复合粒子可以显著提高TiO2颗粒光催化活性。以甲基橙为模拟污染物,经过光催化试验,证实复合纳米粒子具有较好的光催化活性,降解率达到96.25%。

【Abstract】 Self-assembled TiO2-based air-water interfacial particles with nano structure were soaked into silver nitrate (AgNO3) aqueous solution and Ag-TiO2 composite nanoparticles were obtained by the heat-treatment at 400 oC. The composite nanoparticles were characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and ultraviolet visible spectrum (UV-Vis). The results show that the Ag-TiO2 particles at 400 oC could significantly enhance the photocatalytic activity of the TiO2 particles. Methyl orange was used as the degradable agent in photocatalytic experiment. The results indicate that methyl orange could be degraded 96.25% by Ag-TiO2 nanoparticles under the optimal conditions. It is concluded that the Ag-TiO2 composite nanoparticles posses good photocatalysis activity.

【关键词】 银-二氧化钛自组装光催化
【Key words】 Ag-TiO2self-assemblyphotocatalysis
【基金】 国家自然科学基金(20974045);江苏省自然科学基金(BK2009385);巢湖学院自然科学基金(XLZ-200902)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2012年09期
  • 【分类号】TB383.1
  • 【被引频次】9
  • 【下载频次】224
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