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硝化细菌纤维素的制备及表征

Preparation and Characterization of Nitrated Bacterial Cellulose

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【作者】 杨强彭碧辉梁岗罗庆平裴重华

【Author】 YANG Qiang 1,PENG Bi-hui 1,LIANG Gang 2,LUO Qing-ping 1,PEI Chong-hua 1(1.State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials,Southwest University of Science and Technology,Mianyang Sichuan 621010,China;2.Luzhou North Chemical Industries Co.,Ltd.,Luzhou Sichuan 646003,China)

【机构】 西南科技大学四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地泸州北方化学工业有限公司

【摘要】 以细菌纤维素为原料,用硝硫混酸法合成出硝化细菌纤维素(NBC)。结果表明,采用硝硫混酸法合成硝化细菌纤维素未造成细菌纤维素的网状结构明显断裂降解,且合成出的硝化细菌纤维素安定性能达到A级硝化纤维素标准。用差示扫描量热法对产物进行了表征,并计算出硝化细菌纤维素的热分解活化能为212.53kJ/mol,表明硝化细菌纤维素热的稳定性优于硝化棉。

【Abstract】 Nitrated bacterial cellulose(NBC)was synthesized from bacterial cellulose(BC)by nitric-sulfuric acid method.The results showed that the network structure of BC were not obviously degraded by this method and the stability of nitrated bacterial cellulose reached the standard for A degree of nitrocellulose.The thermal decomposition activation energy calculated by differential scanning calorimetry results is 212.53kJ/mol,and the thermal stability of nitrated bacterial cellulose is better than nitrocellulose.

  • 【文献出处】 火炸药学报 ,Chinese Journal of Explosives & Propellants , 编辑部邮箱 ,2012年03期
  • 【分类号】TQ560.1
  • 【被引频次】10
  • 【下载频次】299
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