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新型多磺酸基离子液体催化对甲酚与叔丁醇的烷基化反应(英文)

Alkylation of p-Cresol with tert-Butanol Catalyzed by Novel Multiple-SO3H Functioned Ionic Liquid

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【作者】 鲍少华权南南张敬杨建国

【Author】 BAO Shaohua,QUAN Nannan,ZHANG Jing and YANG Jianguo Shanghai Key Laboratory of Green Chemistry and Chemical Process,Department of Chemistry,East China Normal University,Shanghai 200062,China

【机构】 Shanghai Key Laboratory of Green Chemistry and Chemical Process,Department of Chemistry,East China Normal University

【摘要】 The alkylation of p-cresol with tert-butanol(TBA)to 2-tert-butyl-p-cresol(TBC)catalyzed by a novel multiple-SO3H functioned ionic liquid(IL1)was investigated.Meanwhile,the catalytic activity of this novel ionic liquid was compared with other four traditional ionic liquids.The results showed that IL1 has superior catalytic activity to other four traditional ionic liquids with the conversion of 85.3%and selectivity of 95.2%.Also,the reaction conditions were investigated to obtain the optimum conditions.Operational simplicity,small amount of usage,high activity,reusability and selectivity are the key features of this methodology.

【Abstract】 The alkylation of p-cresol with tert-butanol(TBA)to 2-tert-butyl-p-cresol(TBC)catalyzed by a novel multiple-SO3H functioned ionic liquid(IL1)was investigated.Meanwhile,the catalytic activity of this novel ionic liquid was compared with other four traditional ionic liquids.The results showed that IL1 has superior catalytic activity to other four traditional ionic liquids with the conversion of 85.3%and selectivity of 95.2%.Also,the reaction conditions were investigated to obtain the optimum conditions.Operational simplicity,small amount of usage,high activity,reusability and selectivity are the key features of this methodology.

【基金】 Supported by the National High Technology Research and Development Program of China(2006BAE03B06);Shanghai Leading Academic Discipline Project(B409);Shanghai International Cooperation of Science and Technology Project(06SR07101)
  • 【文献出处】 Chinese Journal of Chemical Engineering ,中国化学工程学报(英文版) , 编辑部邮箱 ,2011年01期
  • 【分类号】O621.251
  • 【被引频次】8
  • 【下载频次】222
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