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高温溶液法生长PZN-9PT弛豫铁电晶体

Study on the Growth of PZN-9PT Single Crystal by Flux Method

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【作者】 龙伟惠增哲李晓娟尹珂

【Author】 LONG Wei,XI Zengzhe,LI Xiaojuan,YIN Ke (School of Materials and Chemical Engineering,Xi’an Technological University,Xi’an 710032,China)

【机构】 西安工业大学材料与化工学院

【摘要】 采用高温溶液法制备了PZN-9PT晶体,研究了晶体相结构、生长形态,表征了其介电、压电和电滞回线等部分电学性能。结果表明,采用高温溶液法可制备出纯钙钛矿结构的PZN-9PT单晶,晶体呈淡黄色多面体形态,晶粒表面的台阶均为直形生长台阶;其三方-四方相转变温度为89℃,居里温度为175℃;[221]切型PZN-9PT单晶的压电常数为230 pC/N,矫顽场为8.8 kV/cm。

【Abstract】 The PZN-9PT single crystal has been prepared by the flux method.The crystal phase structure and the grown morphology of the PZN-9PT crystal have been investigated.The electrical properties such as the dielectric,piezoelectric properties,and the ferroelectric hysteresis loop of the crystal were characterized by the corresponding equipment.The results indicated that PZN-9PT single crystals with pure perovskite structure can be prepared by the flux method.The as-grown PZN-9PT crystals were presented the straw yellow polyhedron.The grain surface is presented the straight steps growth stage.The phase transition temperature from the rhombohedral phase to tetragonal phase is 89 ℃.The courier temperature of the crystal is 175 ℃.The piezoelectric constant of cut PZN-9PT single crystal are 230 pC/N and its coercivity field is 8.8 kV/cm.

【基金】 国家自然科学基金资助项目(50872104、51072155);陕西省科技计划基金资助项目(2010JZ006);陕西省教育厅基金资助项目(10JK904);陕西省重点学科基金资助项目(080503);陕西省薄膜技术与光学检测重点实验基金资助项目(ZSKJ200706);西安工业大学校长基金资助项目(XAGDXJJ0609)
  • 【文献出处】 压电与声光 ,Piezoelectrics & Acoustooptics , 编辑部邮箱 ,2011年01期
  • 【分类号】TM221
  • 【被引频次】6
  • 【下载频次】247
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