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Sb变质后Al-Si合金共晶组织的不均匀性

Un-Uniformity of Eutectic Structure in Al-Si Alloy Modified with Antimony

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【作者】 董光明廖恒成孙国雄韩正铜

【Author】 Dong Guangming1,Liao Hengcheng2,Sun Guoxiong2,Han Zhengtong1(1.School of Mechanical and Electrical Engineering,China University of Mining and Technology,Xuzhou,China;2.School of Material Science and Engineering,Southeast University,Nanjing,China)

【机构】 中国矿业大学机电工程学院东南大学材料科学与工程学院

【摘要】 为了研究Sb变质的Al-13Si-0.4Mg合金中共晶组织的不均匀性,采用液淬技术及光学显微镜考察Sb变质的Al-13Si-0.4Mg合金凝固过程中的组织形成过程。结果发现,在共晶反应初期,先期形成的共晶团的分枝很少,此时形成的共晶组织往往较粗大,表现为共晶Si片较厚、片间距大、分枝少;而此后的共晶反应过程中,共晶团的分枝增加,形成的共晶组织较细小,表现为共晶Si片较薄、片间距小、分枝密集。组织不均匀性的主要原因是Sb在共晶固/液界面前沿的富集程度不同,导致了Sb在共晶Si表面的吸附数量不同,从而影响了共晶Si的生长速度。

【Abstract】 Microstructure evolution of Sr modified Al-13Si-0.4Mg alloy during solidification process was observed by quenching and OM(optical microscope) to understand the un-uniformity of eutectic structure in the alloy.The results show that,during the initial stage of eutectic reaction,coarse eutectic structure is created in the alloy as a result of low branches in formed eutectic colony,characterized by thick eutectic Si flakes with wide lamellar spacing and a few branches.With advancing in reaction,eutectic grain is gradually refined due to the increase of branches in eutectic colony,characterized by thin eutectic Si flakes with narrow lamellar spacing and a lot of branches.Different enrichment of Sb at eutectic solid-liquid solidification front results in the different absorption coefficient of Sb on surface of eutectic Si,affecting the growth velocity of eutectic Si,which is responsible for the un-uniformity of structure in the alloy.

【关键词】 Al-Si合金组织的不均匀性变质
【Key words】 Al-Si AlloyMicrostructure Un-uniformitySbModification
【基金】 江苏省自然科学基金资助项目(BK2004069)
  • 【文献出处】 特种铸造及有色合金 ,Special Casting & Nonferrous Alloys , 编辑部邮箱 ,2011年05期
  • 【分类号】TG292
  • 【被引频次】16
  • 【下载频次】213
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