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无卤阻燃三元乙丙橡胶燃烧性能的影响因素

Effect Factors of the Combustion Property of Halogen-free Flame-retardant EPDM

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【作者】 李波; 张立群; 马晨; 田明; 吕庆; 庄澎;

【Author】 LI Bo1,ZHANG Li-qun1,MA Chen1,TIAN Ming1,LV Qing2,ZHUANG Beng2(1.Beijing University of Chemical Technology,Beijing 100029,China;2.Jiangyin Haida Rubber and Plastic Co.Ltd.,Wuxi 214423,China)

【机构】 北京化工大学北京市新型高分子材料制备与加工重点实验室; 北京化工大学教育部纳米材料重点实验室; 江阴海达橡塑股份有限公司;

【摘要】 使用锥形量热仪(Cone Calorimeter,简称CONE)系统地研究了无机氢氧化物的种类及用量、阻燃协效剂、炭黑和增塑剂等对三元乙丙橡胶燃烧特性的影响,并分析了燃烧产物的形貌,揭示了它们在EPDM燃烧过程中的作用。结果表明,高填充氢氧化物的EPDM胶料适用于制备低烟无卤阻燃橡胶材料;添加红磷和硼酸锌可促进胶料燃烧时的成炭行为,有助于提升阻燃性,但会增大发烟量;加入炭黑有助于提升胶料多项阻燃性能,加入增塑剂不利于胶料的阻燃性。

【Abstract】 Effects of the types and content of inorganic hydroxides,synergistic flame retardants(red phosphorus and zinc borate),carbon black and plasticizing agent(paraffin oil) on the combustion characteristic of EPDM were systematically researched by using Cone Calorimeter,and the morphologies of combustion products were also analyzed to reveal their roles of the additives during the combustion process of EPDM.The results showed that the EPDM blends filled with a large amount of hydroxides were suited to prepare the halogen-free flame-retardant blends;The carbon-forming behavior of the blends during the combustion process and the flame proofness could be developed by adding red phosphorus and zinc borate,at the same time the more smoke was produced.The flame-retardant properties were developed by adding carbon black.The flame retardant were not developed by adding the plasticizing agent.

  • 【文献出处】 特种橡胶制品 ,Special Purpose Rubber Products , 编辑部邮箱 ,2011年01期
  • 【分类号】TQ333.4
  • 【被引频次】13
  • 【下载频次】587
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