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沸石的改性及其对水源水中氨氮去除的研究

Research on zeolite modification and its removal of ammonia-nitrogen in source water

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【作者】 刘通闫刚姚立荣陆丽巧赵婷婷张文艺

【Author】 LIU Tong1,YAN Gang2,YAO Li-rong2,LU Li-qiao2,ZHAO Ting-ting2,ZHANG Wen-yi2(1.Huatian Engineering & Technology Corporation,MCC,Ma’anshan 243005,China;2.School of Environmental & Safety Engineering,Changzhou University,Changzhou 213164,China)

【机构】 中冶华天工程技术有限公司常州大学环境与安全工程学院

【摘要】 以水源水为处理对象,通过对沸石进行酸、盐、高温改性和氨氮去除试验,考察沸石粒径、接触时间、温度等因素对氨氮去除的影响。结果表明,经盐(NaCl)改性的沸石对氨氮有较高的去除率,对于氨氮浓度为4.43mg/L的水源水,在粒径0.8~1.7mm、温度25℃的条件下,经15min接触,氨氮浓度可降至0.3mg/L,去除率可达93.2%。改性沸石对氨氮的去除机理是沸石表面(及内部孔隙)吸附作用和离子交换作用。对于普通自来水厂,只需将快滤池中常用的石英砂部分替换成改性沸石即可有效去除饮用水中的氨氮。经测算其投资仅增加33~39元/m3,运行费用基本不变。

【Abstract】 High concentration of ammonia-nitrogen in source water is extremely harmful to human health.How to remove ammonia-nitrogen efficiently and at low-cost in tap water has been a tough problem for numerous water plants.In this study,experiments were conducted using source water to investigate the effect of zeolite size,contact time and temperature upon the ammonia-nitrogen removal by zeolite modification with acid,salt and high temperature and the ammonia-nitrogen removal test.The results show that NaCl-modified zeolite has better removal efficiency.Under the condition of particle size being 0.8 ~ 1.7 mm,temperature of 25℃,contact time for 15 min,the ammonia-nitrogen concentration in source water is decreased from 4.43 mg /L to 0.3mg /L,while the removal rate comes up to 93.2%.The mechanism of removing ammonia-nitrogen by modified zeolite is zeolite surface(and internal pore) adsorption and ion exchange.Using modified zeolite partially to replace the common quartz sand in fast filer is only needed for ordinary water plants to remove ammonia-nitrogen effectively in drinking water.Financial estimation show that the investment increases only by 33 ~ 39 yuan /m3,while the running costs basically un-increases.

【关键词】 改性沸石水源水氨氮CODMn
【Key words】 modified zeolitesource waterammonia-nitrogenCODMn
【基金】 江苏省自然科学基金项目(SBK200930405);“十一五”国家科技重大专项(2008ZX07101007-01);常州市自然科学基金项目(CS20100002)
  • 【文献出处】 水文地质工程地质 ,Hydrogeology & Engineering Geology , 编辑部邮箱 ,2011年02期
  • 【分类号】X703
  • 【被引频次】37
  • 【下载频次】778
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