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稀土β成核剂改性PPR力学与结晶性能研究

Study on Mechanical Properties and Crystallization of PPR Modified by Rare Earth β Nucleating Agent

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【作者】 丁会利张梅聂鑫张洁郑德

【Author】 Ding Huili 1 Zhang Mei 1 Nie Xin 1 Zhang Jie 1 Zheng De 2 1 Institute of Polymer Sci. and Eng., Hebei University of Technology, Tianjin 300130, China 2 Guangdong Winner Functional Materials Co. Ltd., Foshan 528521, China

【机构】 河北工业大学化工学院高分子科学研究所广东炜林纳功能材料有限公司

【摘要】 研究了稀土β成核(剂WBG-1改)性无规共聚聚丙烯(PPR的)力学行为,并利用热台偏光显微镜和广角X射线衍射观察和分析了WBG-1改性PPR的晶型和结晶形态。结果表明:随着WBG-1用量的增加,PPR的拉伸强度、弯曲强度和弯曲模量呈现先降后升趋势,而其冲击强度和断裂伸长率呈现先升后降的趋势,且在WBG-1用量为0.3%时均达到最大值;添加WBG-1后改,性PPR的β晶含量和结晶速度明显提高。

【Abstract】 The mechanical properties and crystallization of propylene-ethylene random copolymer (PPR) modified by rare earth β nucleating agent (WBG-1) were studied through SEM, WAXD and PLM. The results show that: with increasing of WBG-1, the tensile strength, bending strength and modulus of modified PPR decrease firstly and then increase, but the impact strength and elongation at break increase firstly and then decrease; and when the nucleating agent content is 0.3%, the properties reach to the peak value. β-crystal form contents and the rate of crystallization of modified PPR mixing WBG-1 are significantly increased .

【基金】 河北省自然科学基金资助项目(E2010000122)
  • 【文献出处】 塑料科技 ,Plastics Science and Technology , 编辑部邮箱 ,2011年04期
  • 【分类号】TQ325.14
  • 【被引频次】13
  • 【下载频次】248
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