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含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用
Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles
【摘要】 由于氟原子赋予的特殊性能,含氟杂环化合物在医药、农药及特种功能材料等研究领域受到广泛关注.综述近年来本研究团队常用的一些新颖含氟砌块如含氟酮酸酯、含氟亚胺酰卤等的设计合成及其在含氟杂环化合物合成中的应用进展.
【Abstract】 Fluorinated heterocycles have attracted substantial research attention in the fields of medicine, pesticide and special-function materials,which have special properties caused by fluorine atoms.This review highlights the recent development on the synthesis of novel fluorine-containing building blocks, such as fluorine-containing keto esters and fluorine-containing imidoyl halides,and on their applications to the preparation of fluorinated heterocycles.
【关键词】 含氟砌块;
含氟杂环化合物;
酮酸酯;
亚胺酰卤;
【Key words】 fluorine-containing building block; fluorinated heterocycle; keto ester; imidoyl halide;
【Key words】 fluorine-containing building block; fluorinated heterocycle; keto ester; imidoyl halide;
【基金】 国家自然科学基金资助项目(20772079,21072127,21032006,21072128);上海市科委基金资助项目(08JC1409900,10JC1405600)
- 【文献出处】 上海大学学报(自然科学版) ,Journal of Shanghai University(Natural Science Edition) , 编辑部邮箱 ,2011年04期
- 【分类号】O626
- 【被引频次】9
- 【下载频次】497