【摘要】 在流化催化裂化（FCC）汽油中加入磷钨杂多酸季铵盐Q₃[PO₄（WO₃）₄](Q=[C₁₆H₃₃NMe₃]⁺+[C₁₈H₃₇NMe₃]⁺)/H₂O₂实现了液—液高效催化氧化降烯烃。研究结果表明:在H₂O₂用量2.5mL、反应时间1h、反应温度60℃、m（汽油）:m（催化剂）=40:1、pH值3.3的条件下,FCC汽油中烯烃体积分数降到了23.56%,而汽油辛烷值基本保持不变。更多还原

【Abstract】 The olefin content of FCC（fluid catalytic cracking） gasoline was reduced by a liquid-liquid phase and high efficiency catalytic oxidation system containing heteropolyphosphatotungstate Q₃[PO₄ （WO₃）₄](Q=[C₁₆H₃₃NMe₃]⁺+[C₁₈H₃₇NMe₃]⁺) and hydrogen peroxide.It was shown that the catalytic system made the olefin content of FCC gasoline decrease by 23.58%under the optimal reaction conditions,i.e.,the amount of H₂O₂ 2.5 mL,reaction time 1 h,reaction temperature 60℃,the ratio of FCC gasoline and catalyst 40:1 and pH 3.3.The olefin content of FCC gasoline dealt with this system was less than 35%,while the octane number of gasoline did not decrease,which has reached the national standard of clean FCC gasoline.更多还原