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铁镍触媒合成金刚石内部包裹体的研究

Study on Inclusion in Diamond Synthesized from Fe-Ni Catalyst

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【作者】 张洋董凤霞万素琴谢晓军宫丽晶王运峰邱利霞

【Author】 ZHANG Yang1,2,DONG Feng-xia3,WAN Su-qin4,XIE Xiao-jun2, GONG Li-jing2,WANG Yun-feng2,QIU Li-xia2(1.College of Science,Zhongyuan University of Technology,Xinzheng 451191,Henan Province,China; 2.College of Physics,Jilin University,Changchun 130012,China; 3.College of Chemistry,Jilin University,Changchun 130012,China;(4.Institute of Theoretical Chemistry,Jilin University,Changchun 130021,China)

【机构】 中原工学院理学院吉林大学物理学院吉林大学化学学院吉林大学理论化学研究所

【摘要】 分析铁镍触媒合成金刚石内部的包裹体成分及形成原因.结果表明:金刚石晶体中的包裹体主要以FeNi合金和Fe3C形式存在;随着生长速度加快,金刚石内部包裹体的点状分布逐渐增多;在不同温度下,进入金刚石晶体内部包裹体的方式不同;随着包裹体的增多,合成的金刚石晶体硬度降低.通过调整合成工艺,合成了包裹体含量极少、粒度约为0.6~0.7 mm的金刚石单晶.

【Abstract】 The authors studied the inclusions in diamond synthesized from Fe-Ni catalyst and formation mechanism.The results show that the main components of the inclusions were Fe-Ni catalyst and Fe3C in diamond,and the puncate distribution of the inclusions increased gradually with the increasing growth rate of the diamond,and the growth models for the incorporation of the inclusions were different at different temperatures,and the hardness of the synthesized diamond decreased with the increasing of the inclusions in diamond.The authors synthesized the extra low inclusions,and the size of the diamond single cryststals is about 0.6—0.7 mm by means of the adjustment of the synthesis technology.

【关键词】 金刚石包裹体铁镍触媒穆斯堡尔谱
【Key words】 diamondinclusionFe-Ni catalystMssbauer spectrum
【基金】 国家自然科学基金(批准号:11074093);中国高校基本科研业务费项目(批准号:200903320)
  • 【文献出处】 吉林大学学报(理学版) ,Journal of Jilin University(Science Edition) , 编辑部邮箱 ,2011年05期
  • 【分类号】TQ164
  • 【被引频次】5
  • 【下载频次】167
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