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恒电流电解-BCO分光光度法测定纯铜中铜含量不确定度的评定

UNCERTAINTY OF DETERMINATION OF COPPER IN PURE COPPER BY ELECTROLYTIC-SPECTROPHOTOMETRIC METHOD

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【作者】 马冲先曹宏燕钱芳华

【Author】 Ma Chongxian1,Cao Hongyan2,Qian Fanghua1 [1.Testing Center,Shanghai Research Institute of Materials,Shanghai200437,China; 2.Technology Center,Wuhan Iron & Steel(Group) Company,Wuhan430080,China]

【机构】 上海材料研究所检测中心武汉钢铁(集团)公司技术中心

【摘要】 对采用恒电流电解-BCO分光光度法测定纯铜中铜含量的不确定度进行了评定。对测量重复性、电解重量法、光度法等影响测量结果的不确定度分量进行了分析和量化。当纯铜中铜的质量分数为99.93%时,扩展不确定度为0.01%k,=2。

【Abstract】 The uncertainty of measurement was evaluated for the determination of copper in pure copper by electrolytic-spectrophotometric method.The uncertainty components of the measurement results,including repeatability of measurement results,electrolytic method and spectrophotometry were analyzed and quantified.The expanded uncertainty of measurement result was 0.01%(k=2) as the copper mass fraction in pure copper was 99.93%.

  • 【文献出处】 化学分析计量 ,Chemical Analysis and Meterage , 编辑部邮箱 ,2011年01期
  • 【分类号】TG115.335
  • 【下载频次】74
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