【摘要】 在有机碱1,8-二氮杂双环[5,4,0]+-7烯(简称DBU)存在下的醇溶剂中,以四-α-(3-吡啶氧基)-邻苯二腈与无水氯化钴为原料,通过模板法合成了四-α-(3-吡啶氧基)-酞菁钴[α-(PyO)4PcCo]。以紫外-可见吸收光谱、红外光谱、拉曼光谱以及激光解析飞行质谱(MALDI-TOF)等手段对其结构进行了表征,并研究了四-α-(3-吡啶氧基)-酞菁钴在DMF、THF、CH2Cl2中的聚集状态,研究结果表明:在1～9×10-6 mol·L-1范围内,四-α-(3-吡啶氧基)-酞菁钴在三种溶剂中都以单体的形式存在。更多还原

【Abstract】 Tetra-α-(3-pyridyloxy) phthalocyanine cobalt [α-(PyO)4PcCo] was synthesized from 3-(3-pyridyloxy)phthalonitrile and anhydrous cobalt chloride by template reaction in n-amyl alcohol solvent in the presence of 1,8-diazabicyclo-undec-7-ene(DBU).It was characterized by using UV-Vis spectrum,IR spectrum,Raman spectrum and MALDI-TOF mass spectrometry.The aggregative behavior of α-(PyO)4PcCo was studied in DMF,THF and CH2Cl2 solvents at the range of 1～9×10-6mol·L-1.The results show that molecules of α-(PyO)4PcCo are present as monomers in DMF,THF and CH2Cl2.更多还原