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LaMnO3纳米空心球的制备及其催化性能研究

SYNTHESIS AND CATALYTIC PERFORMANCE OF LaMnO3 HOLLOW NANOSPHERE

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【作者】 张晓雪张婷顾福博王志华郭广生

【Author】 ZHANG Xiaoxue ZHANG Ting GU Fubo WANG Zhihua GUO Guangsheng(State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing,100029,China)

【机构】 北京化工大学化工资源有效利用国家重点实验室

【摘要】 采用碳微球模板法制备了LaMnO3纳米空心球催化剂,采用热重分析、X射线衍射、扫描电子显微镜、透射电子显微镜和比表面积分析仪(BET)对催化剂进行了表征,利用程序升温反应评价了催化剂用于消除汽车尾气中CO和碳氢化合物的催化活性.通过系统的研究发现,采用煅烧温度600℃制备的LaMnO3纳米空心球具有最高的催化活性.

【Abstract】 LaMnO3 hollow nanospheres were prepared using carbon microballons as templates.The samples were characterized by means of TG-DTA,XRD,SEM,TEM and BET.The catalytic activities of the nanospheres for the conversion of CO and hydrocarbon compounds into CO2 were evaluated in a temperature programmed microreactor system.It was found that different calcination temperatures resulted in the formation of the nanospheres with different shapes,specific surface areas and catalytic activity.The sample calcined at 600 ℃ has a diameter of 30 nm and a specific surface area of 51.99 m2 ·g-1,and has the highest catalytic activity for CO and hydrocarbon conversion.

【关键词】 LaMnO3模板法纳米空心球催化剂
【Key words】 LaMnO3 perovskitetemplate methodhollow nanospherecatalyst.
【基金】 国家自然科学基金(20875007);北京市科学技术计划项目(Z080003032208012)资助
  • 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,2011年04期
  • 【分类号】O643.36
  • 【被引频次】8
  • 【下载频次】371
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