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腐殖酸与EDTA对高铁酸钾降解水中孔雀石绿影响的研究

Study on the Effect of Humic Acid and EDTA on the Degradation of Malachite Green in Aqueous Solution by Potassium Ferrate

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【作者】 金士威; 张旭; 欧阳贻德; 李玲; 何秉忠; 廖涛;

【Author】 JIN Shi-wei1,ZHANG Xu1,OUYANG Yi-de1,LI Ling1,HE Bing-zhong1,LIAO Tao2(1.School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology/Key Lab for Green Chemical Process of Ministry of Education,Wuhan 430073,China;2.Institute for Farm Products Processing and Nuclear Agricultural Technology,Hubei Academy of Agricultural Sciences,Wuhan 430064,China)

【机构】 武汉工程大学化工与制药学院/绿色化工过程教育部重点实验室; 湖北省农业科学院农产品加工与核农技术研究所;

【摘要】 在高铁酸钾与孔雀石绿的质量比为10∶1,pH值为7.0的条件下,考察腐殖酸与EDTA对高铁酸钾降解水体中孔雀石绿的影响。结果表明,加入少量的腐殖酸和EDTA溶液,孔雀石绿溶液的吸光度降低,有利于高铁酸钾对孔雀石绿的降解;EDTA的加入量过多时,反而抑制高铁酸钾对孔雀石绿的降解;加入2.0 mL腐殖酸和4.0 mL EDTA溶液降解2 h效果较好。

【Abstract】 In the condition of the mass ratio of potassium ferrate to malachite green at 10∶1 and pH 7.0,the effects of humic acid and EDTA on the degradation of malachite green by potassium ferrate was studied.The results showed that the absorbance of malachite green solution decreased when adding a small amount of humic acid and EDTA solution.Thus,humic acid and EDTA were benefit to the degradation of malachite green by potassium ferrate.However,when added excessive EDTA,it inhibited the degradation of malachite green.In summary,effective degradation could be obtained when the amount of humic acid and EDTA was 2.0 mL and 4.0 mL respectively;and degradation time was 2 hours.

【关键词】 孔雀石绿; 高铁酸钾; 腐殖酸; EDTA; 降解;
【Key words】 malachite green; potassium ferrate; humic acid; EDTA; degradation;
【基金】 湖北省教育厅青年基金项目(Q20091503)
  • 【文献出处】 湖北农业科学 ,Hubei Agricultural Sciences , 编辑部邮箱 ,2011年17期
  • 【分类号】X703.1
  • 【被引频次】2
  • 【下载频次】154
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