【摘要】 通过对镍的芳基磺酸化合物[Ni(H2O)6](1,5-nds)(M)(1,5-nds=1,5-萘二磺酸)与有机胺的固-汽反应性能进行研究,表明母体化合物能够定量地吸附有机脂肪胺形成稳定的吸附产物,且反应具有选择性和优先性,反应过程中还伴随有颜色的变化,具备作为有机胺化学感应器的基本性能。反应产物通过EA、TGA、IR和PXRD进行表征。更多还原

【Abstract】 The solid-vapor reaction property of nickle(Ⅱ) arenesulfonate compound,namely [Ni(H2O)6](1,5-nds)(M)(1,5-nds=1,5-naphthalenedisulfonate),was investigated,and the reaction products were characterized by EA,TGA,IR and PXRD.The results demonstrated that solid material M can quantitatively take up to primary alkyl amine vapors and form stable coordination compounds.The reaction process of M with amines was selective,preferential and accompanied by a color change,indicating that the title compound could be designed as an amine-sensitive material.更多还原