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γ射线辐照处理竹材化学组分及结晶度变化研究
Study on Chemical Compositions and Crystallinity Changes of Bamboo Treated with γ Rays
【摘要】 利用核磁共振波谱仪和X射线衍射仪,对γ射线辐照处理前后的竹材进行CP/MAS13C-NMR图谱、XRD光谱分析,得出竹材细胞壁主要化学组分在辐照过程中结构和性质的变化规律。随着辐照剂量升高,竹材纤维素结晶度呈现先升高后降低的趋势,半纤维素发生降解,木质素由非酚型向酚型转变。
【Abstract】 The structures and qualities of main chemical compositions in cell wall of bamboo treated with γ rays were tested by nuclear magnetic resonance spectrometer(NMR) and X-ray Diffraction(XRD).The result indicated that the bamboo crystallinity increased at the beginning of irradiation process,while the crystallinity reduced when the irradiation dose was raised to about 100 kGy.During the whole irradiation process,hemicellulose degraded,and with the irradiation doses increased the non-phenolic lignin changed to the phenolic.
【关键词】 竹材;
γ射线;
辐照;
化学组分;
结晶度;
【Key words】 Bamboo; γ rays; Irradiation; Chemical compositions; Crystallinity;
【Key words】 Bamboo; γ rays; Irradiation; Chemical compositions; Crystallinity;
【基金】 国家“十一五”科技支撑课题(2008BADA9B03)资助
- 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2011年07期
- 【分类号】S781.9
- 【被引频次】20
- 【下载频次】197