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铁炭微电解工艺对高硝态氮制药废水的脱氮效能

Study on Nitrogen Removal Efficiency of Ferric-carbon Micro-electrolysis Process in Treatment of High Nitrate Nitrogen Pharmaceutical Wastewater

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【作者】 周健陈博陈垚龙腾锐胡斌

【Author】 ZHOU Jian,CHEN Bo,CHEN Yao,LONG Teng-rui,HU Bin (Key Laboratory of Three Gorges Reservoir Region’s Eco-Environment <Ministry of Education>, Chongqing University,Chongqing 400045,China)

【机构】 重庆大学三峡库区生态环境教育部重点实验室

【摘要】 以高硝态氮、难降解的有机制药废水为处理对象,探讨了铁炭微电解工艺对其脱氮效能及影响因素。结果表明:填料粒径、pH值、铁炭比、气水比、停留时间等因素均对铁炭微电解系统的脱氮效能有显著影响;在铁屑和活性炭粒径均为35目、pH值为3、Fe/C值为3∶1(体积比)、气水比为5∶1、停留时间为1.5 h的最佳条件下,当进水TN、NH4+-N和NO3--N的平均浓度分别为823、30和793 mg/L,BOD5/COD值为0.1时,铁炭微电解系统对TN、NH4+-N和NO3--N的平均去除率分别可达到51.5%、70%和50.94%。

【Abstract】 The nitrogen removal efficiency and influence factors of ferric-carbon micro-electrolysis process in treatment of high nitrate nitrogen and refractory organic pharmaceutical wastewater were investigated.The results show that media size,pH,Fe/C ratio,air-water ratio,reaction time and so on have significant effect on the nitrogen removal efficiency of ferric-carbon micro-electrolysis system.Under the optimal conditions of iron and carbon sizes of 35 mesh,pH of 3,Fe/C ratio of 3 ∶1,air-water ratio of 5 ∶1 and retention time of 1.5 h,the removal rates of TN,NH+4-N,NO-3-N are 51.5%,70% and 50.94% respectively,when the influent TN,NH+4-N,NO-3-N and BOD5/COD are 823 mg/L,30 mg/L,793 mg/L and 0.1 respectively.

【基金】 国家水体污染控制与治理科技重大专项(2008ZX07315-005)
  • 【文献出处】 中国给水排水 ,China Water & Wastewater , 编辑部邮箱 ,2011年09期
  • 【分类号】X703
  • 【被引频次】15
  • 【下载频次】470
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