节点文献

FEP纤维的等离子体表面改性

Plasma surface modification of FEP fiber

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 褚国红李辉何颖源张书香

【Author】 CHU Guo-hong1,2,3,LI Hui2,3,HE Ying-yuan2,ZHANG Shu-xiang1,2,3 (1.Material Science and Engineering College,Beijing University of Chemical Technology,Beijing 100029,China; 2.Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials, School of Chemistry and Chemical Engineering,University of Ji’nan,Ji’nan 250022,China; 3.Shandong Engineering Research Centre for Fluorinated Material,Ji’nan 250022,China)

【机构】 北京化工大学材料科学与工程学院济南大学化学化工学院山东省氟化学化工材料重点实验室山东省氟材料工程技术研究中心

【摘要】 以空气气氛对聚全氟乙丙烯(FEP)纤维进行等离子体处理,利用SEM、DSC、XPS对改性前后纤维的性能及形貌进行表征,并测试水在纤维表面的接触角。等离子体处理后纤维的表面发生了C—F键断裂,表面形貌变得粗糙,O原子含量增加4.65%,F原子含量降低4.37%,O/C、F/C原子含量比分别由0.19和0.28变为0.25和0.22,但DSC结果表明结晶度未发生变化;水在纤维表面的接触角由改性前的112.3°降至改性后的54.1°,纤维亲水性得到明显增强。

【Abstract】 The FEP fibers treated by air plasma were characterized by DSC,SEM and XPS.The contact angle of FEP fiber against water was measured.The results of DSC showed that the crystallinity of FEP fiber was not affected by air plasma treatment.The surface morphology became rough after plasma treatment.The atomic content of O has increased 4.65%.The atomic content of F reduced 4.37%.The cleavage of C—F caused by plasma etch induced the atomic content ratio of O/C and F/C changed from 0.19 and 0.28 to 0.25 and 0.22 respectively.The contact angle against water of FEP fiber decreased from 112.3 to 54.1° after the plasma treatment.The hydrophilicity of the FEP fiber was enhanced remarkably through air plasma treatment.

【关键词】 FEP纤维等离子体表面改性亲水性
【Key words】 FEP fiberplasmasurface modificationhydrophilicity
【基金】 国家科技支撑计划资助项目(2006BAE02A01)
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,2011年07期
  • 【分类号】TQ340.65
  • 【被引频次】2
  • 【下载频次】216
节点文献中: 

本文链接的文献网络图示:

本文的引文网络