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大理石粉/NR复合材料的制备与性能研究

Preparation and Characterization of Marble Powder/Natural Rubber Composites

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【作者】 王继虎陈有双唐忠锋陶冶

【Author】 WANG Ji-hu~1,CHEN You-shuang~2,TANG Zhong-feng~2,TAO Ye~3(1.College of Chemistry and Chemical engineering,Shanghai University of Engineering Science,Shanghai 201620,China;2.Department of Biological and Chemical engineering,Guangxi University of Technology,Liuzhou 545006,China;3.Shanghai BoDa Enterprise Group,Shanghai 201702,China)

【机构】 上海工程技术大学化学化工学院广西工学院生物与化学工程系上海博大企业集团

【摘要】 将石材加工过程中产生的废弃大理石粉碎,采用硬脂酸偶联剂对大理石粉进行改性。将改性后大理石粉混炼到NR中制备复合材料,通过不同测试手段研究材料的性能变化。结果表明,球磨后大理石粉的平均粒径为24.18μm。采用硬脂酸改性后大理石粉添加量为10%时性能最佳,拉伸强度达到20.11MPa。与大理石/NR及纯橡胶材料相比,改性后大理石粉/NR复合材料的耐热性能明显提高。活化后大理石粉作为橡胶填料,可替代炭黑降低橡胶制品生产成本,同时有利于环保。

【Abstract】 Marble powder was modified by stearic acid coupling agent after marble scraps were grinded.Natural rubber/marble powder composites were prepared by direct blending technology.The results showed that the average particle size of marble powder was 24.18μm.The best mechanical properties of composites were obtained after modified marble powder content were 10 percent in the natural rubber,and the tensile strength was 20.11 Mpa.The heat resistance of composites was higher than unmodified marble powder/NR composites.Activated marble powder has excellent reinforcement effect and ideal processing characteristics,and can replace carbon black in rubber to achieve its application.

【基金】 上海高校“085”知识创新工程建设项目(JZ0904);柳州市经委资助项目(柳经通2009159);上海工程技术大学和上海博大集团合作项目(08HG-002);
  • 【文献出处】 高分子通报 ,Polymer Bulletin , 编辑部邮箱 ,2011年06期
  • 【分类号】TB332
  • 【被引频次】3
  • 【下载频次】175
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