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含有POSS的复合型质子交换膜的制备及性能
Preparation and Properties of the POSS-containing Composites as Proton Exchange Membranes
【摘要】 <正>燃料电池作为一种高效环保的绿色能源,有望获得重要应用.作为聚合物电解质膜燃料电池和直接甲醇燃料电池的核心部件,质子交换膜的研制是该领域的热点.针对目前具有产业化规模的
【Abstract】 A naphthylene-containing sulfonated polyaryletherketone(SPAEK) was synthesized as a matrix.A polyazomethine having naphthylene,ether and ketone linkages(PAM) was selected as a molecular-enhanced component.Aimed at improving the properties,a ternary-composite membrane was constructed by incorporating sulfonic acid-functionalized polysilsesquioxane through a sol-gel processing.The morphology of the membranes was studied by SEM.Compared with plain SPAEK and SPAEK/PAM blend,the ternary-composite membranes show higher proton conductivity and selectivity.
【关键词】 质子交换膜;
燃料电池;
聚芳醚酮;
复合;
【Key words】 Proton exchange membrane; Fuel cell; Polyaryletherketone; Composite;
【Key words】 Proton exchange membrane; Fuel cell; Polyaryletherketone; Composite;
【基金】 国家自然科学基金(批准号:50973040);吉林省科技厅-国际合作项目(批准号:20100706)资助
- 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2011年08期
- 【分类号】TM911.4
- 【被引频次】8
- 【下载频次】284