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主链含偶氮电活性聚酰胺材料的合成与性质
Synthesis and Characterization of Novel Electroactive Polyamide with Azo Groups in the Backbone
【摘要】 <正>聚苯胺因其特殊的光学、电学和磁学性质成为最具应用潜力的导电高分子材料.然而结构上的缺陷和不溶不熔的现象限制了聚苯胺的深入研究和应用.苯胺齐聚物具有明确的分子结构和良
【Abstract】 An alternating copolymer,electroactive azo polyamide was prepared by oxidative coupling poly-merization and its characteristics were systematically studied.The polyamide showed both electroactivity and photoactivity.A large enhancement in the dielectric constant of the polymer was achieved utilizing the method of doping the conjugated oligoaniline segments with hydrochloric acid.
【关键词】 偶氮苯;
苯胺齐聚物;
电活性;
光响应;
氧化偶联;
【Key words】 Azobenzene; Oligoaniline; Electroactive; Photoresponsive; Oxidative coupling;
【Key words】 Azobenzene; Oligoaniline; Electroactive; Photoresponsive; Oxidative coupling;
【基金】 国家自然科学基金(批准号:50873045);吉林大学科学前沿与交叉学科创新项目(批准号:398225)资助
- 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2011年08期
- 【分类号】O631.3
- 【被引频次】2
- 【下载频次】191