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热聚合制备分子印迹膜的表面等离子体共振现场监测方法
Novel Method for in situ Monitoring the Polymerization Process of Molecularly Imprinted Films by Surface Plasmon Resonance
【摘要】 <正>分子印迹是近年来发展起来的一种对某一特定模板分子具有选择性的聚合物的合成方法[1,2].20世纪80年代分子印迹技术就被应用于生物传感器中.与传统的酶、抗体分子等自然接受体相比,利用分子印迹膜(Molecularly imprinted films,MIFs)制备的生物传感器优点更多,应用范围更广.随着生物
【Abstract】 Molecularly imprinted films(MIFs) were prepared and monitored by in situ surface plasmon resonance(SPR) on the surface of gold substrate.Real-time kinetics of polymerization processes were obtained.That would be helpful to investigate the details of free radical reaction.The MIFs exhibited good adsorption ability to template TNT molecules.The novel method of monitoring MIFs formation will provide important data for {delicately} constructing SPR sensor chips based on MIFs.
【关键词】 表面等离子体共振;
分子印迹膜;
现场监测;
【Key words】 Surface plasmon resonance(SPR); Molecularly imprinted film; In situ monitoring;
【Key words】 Surface plasmon resonance(SPR); Molecularly imprinted film; In situ monitoring;
【基金】 国家自然科学基金(批准号:20771015);高等学校学科创新引智计划(批准号:B07012)资助
- 【文献出处】 高等学校化学学报 ,Chemical Journal of Chinese Universities , 编辑部邮箱 ,2011年02期
- 【分类号】O647
- 【被引频次】5
- 【下载频次】296