【摘要】 在水热条件下合成了配位聚合物[Co(H2O)6]·[Co(phen)2(H2O)2]2·(BTC)2.24·6H2O(phen=1,10-邻菲罗林,BTC=均苯三甲酸),并通过元素分析,IR光谱,TGA和单晶X射线衍射对其进行了表征.结构表明该化合物属于单斜晶系,空间点群P2(1)/c.晶体的不对称结构单元中包含1个均苯三甲酸离子和2个六配位的金属Co(Ⅱ)中心,分别位于八面体配位几何CoN4O2和CoO6中心,形成2个单核阳离子[Co(H2O)6]2+和[Co(phen)2(H2O)2]2+.氢键(O—H…O)将体系内独立的部分连接成具有三维结构的超分子.利用循环伏安法对其电化学行为进行了研究.更多还原

【Abstract】 The complex [Co(H2O)6]·[Co(phen)2(H2O)2]2·(BTC)2·24.6H2O(H3BTC=benzene-1,3,5-tricarboxylic acid,phen =1,10-phenanthroline)was synthesized by the hydrothermal reaction and characterized by single crystal X-ray diffraction analysis,element analysis,TGA,and infrared spectrum.The result shows that the crystal structure belongs to monoclinic system,space group P2(1)/c.The asymmetrical structure unit of the crystal consists of one benzene-1,3,5-tricarboxylic acid ion and two six-coordinational metal Co(Ⅱ) centers,which locate in octahedron MN2O4 and MO6,respectively forming two mononuclear cations [Co(H2O)6]2+ and [Co(Phen)2(H2O)2]2+.The three isolated structure are linked further by hydrogen bonds(O—H…O) to three dimensional supremolecular structure.The cyclic volatmmetric behavior of the complex was also investigated for the definition of the identity of the couple of redox peaks.更多还原