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采用蛇纹石石棉制备纳米纤维白炭黑

Preparation of Silica Nano-fibers With Chrysotile

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【作者】 李世青倪文刘波巩媛媛杨淑敏

【Author】 Li Shiqing1,2,Ni Wen1,Liu Bo3 Gong Yuanyuan2,Yang Shumin2(1.School of Civil and Environment Engineering,University of Science and Technology Beijing,Beijing 100083;2.Technology Center, Shougang Environmental Protection Industry Department,Beijing 100041;3.College of Chemical and Emvivonmental Engineering, Shandong University of Science and Technology, Qingdao 266510,China)

【机构】 北京科技大学土木与环境工程学院首钢总公司环保产业事业部设计技术中心山东科技大学化学与环境工程学院

【摘要】 研究一种制备高品质纳米白炭黑的方法,以蛇纹石石棉为原料,经过酸蚀处理后,制备纳米纤维白炭黑,采用X射线衍射和扫描电镜分析不同浓度下酸蚀的产物,研究不同酸浓度对产物的成分及微观形貌的影响。结果表明:蛇纹石石棉纤维表面存在大量的OH-,在酸性条件下,OH-易于与H+反应而导致Mg2+裸露,在H+足够的情况下,MgO也被完全溶出,残余固体是一种SiO2纯度很高的纳米纤维状物质,SiO2的质量分数为72.63%,而且在一定程度上继承了蛇纹石石棉的纤维状结构。

【Abstract】 A method of producing silica nano-fibers was researched.The fibers were made from chrysotile by acid pickling.By XRD and SEM,the micro-mechanism and component of the products were observed.The results showed that there were a plenty of OH-on the surface of chrysotile fibers.OH-was easily acted with H+ in acid,and then Mg2+ was exposited.If the acid was superfluous,MgO was removed completely.The leaved solid was almost pure SiO2 with mass fraction of 72.63%,which was mainly silica nano-fibers.The silica nano-fibers had the same shape of chrysotile fibers.

【关键词】 蛇纹石石棉纳米纤维酸蚀
【Key words】 chrysotilenano-fiberacid pickling
  • 【文献出处】 中国粉体技术 ,China Powder Science and Technology , 编辑部邮箱 ,2011年03期
  • 【分类号】TB383.1
  • 【被引频次】6
  • 【下载频次】171
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