【摘要】 成功合成了两个新型的三苯胺衍生物:三-[4-(4-三氟甲基-1,3-丁二酮)苯基]胺(L1)、三-[4-(4-苯基-1,3-丁二酮)苯基]胺(L2),并使用元素分析、红外、核磁和质谱进行了表征,通过单晶X-射线衍射分析,发现分子具有D-(π-A)3的结构。更多还原

【Abstract】 Two triphenylamine-based derivatives that can be used as two-photon absorption chromophore,tris{4-[4-(3-trifluoromethyl-3-oxopanoyl)]phenyl}amine(L1) and tris{4-[4-(3-phenyl-3-oxopanoyl)] phenyl} amine(L2) were successfully synthesized and fully characterized by elemental analysis,IR,1H NMR and MS.The single crystal X-ray diffraction analysis showed that the molecules possess D-(π-A)3 structures.更多还原