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Electrochemical performance of nickel hydroxide doped with multi-wall carbon nanotubes

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【作者】 李延伟尹周澜姚金环赵卫民刘长久钟胜奎

【Author】 LI Yan-wei1,2,YIN Zhou-lan1,YAO Jin-huan2, ZHAO Wei-min2,LIU Chang-jiu2,ZHONG Sheng-kui1,2 1.School of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China; 2.College of Chemistry and Bioengineering,Guilin University of Technology,Guilin 541004,China

【机构】 School of Chemistry and Chemical Engineering,Central South UniversityCollege of Chemistry and Bioengineering,Guilin University of Technology

【摘要】 Nickel hydroxide doped with multi-wall carbon nanotubes(MCNTs)was synthesized by chemical coprecipitation method. The MCNTs doped nickel hydroxide was used as the electrochemical active material in the positive electrodes of rechargeable alkaline batteries.The powder X-ray diffraction(XRD)analysis shows that the addition of MCNTs induces more structural defect within the crystal lattice of the nickel hydroxide.The cyclic voltammetry(CV)and electrochemical impedance spectroscopy(EIS) tests demonstrate the better reaction reversibility and lower electrochemical impedance of MCNTs doped nickel hydroxide as compared with the pure nickel hydroxide.The charge/discharge tests show that MCNTs addition can improve the specific discharge capacity and increase the discharge voltage of the nickel hydroxide electrode.

【Abstract】 Nickel hydroxide doped with multi-wall carbon nanotubes(MCNTs)was synthesized by chemical coprecipitation method. The MCNTs doped nickel hydroxide was used as the electrochemical active material in the positive electrodes of rechargeable alkaline batteries.The powder X-ray diffraction(XRD)analysis shows that the addition of MCNTs induces more structural defect within the crystal lattice of the nickel hydroxide.The cyclic voltammetry(CV)and electrochemical impedance spectroscopy(EIS) tests demonstrate the better reaction reversibility and lower electrochemical impedance of MCNTs doped nickel hydroxide as compared with the pure nickel hydroxide.The charge/discharge tests show that MCNTs addition can improve the specific discharge capacity and increase the discharge voltage of the nickel hydroxide electrode.

【基金】 Project(20090450188)supported by China Postdoctoral Science Foundation;Project supported by Postdoctoral Science Foundation of Central South University,China;Project(0991247)supported by Natural Science Foundation of Guangxi Province,China
  • 【文献出处】 Transactions of Nonferrous Metals Society of China ,中国有色金属学报(英文版) , 编辑部邮箱 ,2010年S1期
  • 【分类号】O614.813
  • 【被引频次】9
  • 【下载频次】76
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