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Effective removal of heavy metals from aqueous solutions by orange peel xanthate

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【作者】 梁莎郭学益冯宁川田庆华

【Author】 LIANG Sha1,GUO Xue-yi1,FENG Ning-chuan2,TIAN Qing-hua1 1.School of Metallurgical Science and Engineering,Central South University,Changsha 410083,China; 2.School of Basic Medical Science,Ningxia Medical College,Yinchuan 750004,China

【机构】 School of Metallurgical Science and Engineering,Central South UniversitySchool of Basic Medical Science,Ningxia Medical College

【摘要】 Preparation of orange peel xanthate and its adsorption behaviors of five heavy metals(Cu 2+ ,Cd 2+ ,Pb 2+ ,Zn 2+ and Ni 2+ ) were studied.FTIR spectra,Zeta potentials and TG analysis were used to characterize prepared orange peel xanthate.Effects of various parameters including equilibrium pH,initial metal ion concentration and adsorption time on the adsorption processes for the five metal ions were investigated.It was found that for all five metal ions,the adsorption isotherms agreed Langmuir model very well and the maximum adsorption capacities of Cu2 +,Cd 2+,Pb 2+,Zn 2+and Ni 2+were obtained as 77.60,76.57,218.34,49.85 and 15.45 mg/g,respectively.All adsorption processes can attain equilibrium within 20 min and kinetics was well fitted by psesudo-second order equation.It is proposed that the adsorption mechanism was complexation.

【Abstract】 Preparation of orange peel xanthate and its adsorption behaviors of five heavy metals(Cu 2+ ,Cd 2+ ,Pb 2+ ,Zn 2+ and Ni 2+ ) were studied.FTIR spectra,Zeta potentials and TG analysis were used to characterize prepared orange peel xanthate.Effects of various parameters including equilibrium pH,initial metal ion concentration and adsorption time on the adsorption processes for the five metal ions were investigated.It was found that for all five metal ions,the adsorption isotherms agreed Langmuir model very well and the maximum adsorption capacities of Cu2 +,Cd 2+,Pb 2+,Zn 2+and Ni 2+were obtained as 77.60,76.57,218.34,49.85 and 15.45 mg/g,respectively.All adsorption processes can attain equilibrium within 20 min and kinetics was well fitted by psesudo-second order equation.It is proposed that the adsorption mechanism was complexation.

【关键词】 orange peel xanthateadsorptionheavy metals
【Key words】 orange peel xanthateadsorptionheavy metals
【基金】 Project(50774100)supported by the National Natural Science Foundation of China
  • 【文献出处】 Transactions of Nonferrous Metals Society of China ,中国有色金属学报(英文版) , 编辑部邮箱 ,2010年S1期
  • 【分类号】X703
  • 【被引频次】24
  • 【下载频次】147
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