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孔隙尺寸、盐度和气体组分对水合物相平衡的影响(英文)

Influence of Pore Size,Salinity and Gas Composition upon the Hydrate Formation Conditions

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【作者】 杨明军宋永臣刘瑜陈拥军李清平

【Author】 YANG Mingjun 1,SONG Yongchen 1,LIU Yu 1,CHEN Yongjun 1and LI Qingping 2 1Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education,Dalian Univer-sity of Technology,Dalian 116024,China 2 China National Offshore Oil Corporation Research Center,Beijing 100027,China

【机构】 Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education,Dalian Univer-sity of TechnologyChina National Offshore Oil Corporation Research Center

【摘要】 An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.

【Abstract】 An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.

【关键词】 hydrateequilibriumpore sizesalinitygas composition
【Key words】 hydrateequilibriumpore sizesalinitygas composition
【基金】 Supported by the Key Program of National Natural Science Foundation of China(50736001);the National High Technology Research and Development Program of China(2006AA09A209-5);the Major State Basic Research Development Program of China(2009CB219507)
  • 【文献出处】 Chinese Journal of Chemical Engineering ,中国化学工程学报(英文版) , 编辑部邮箱 ,2010年02期
  • 【分类号】O642.42
  • 【被引频次】21
  • 【下载频次】308
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